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综述:在 UiO 金属有机框架(MOF)节点上构建分子分散的 Cu (I) 活性位 ...
本文聚焦甲烷制乙醇难题,介绍了一种由 Zr 基金属有机框架(UiO-66 MOF)负载的 Cu (I) 催化剂。该催化剂在 100°C、水体系中,能有效催化甲烷氧化生成乙醇,产率达 5196 μmol gCu-1 h-1 ,选择性高达 71%,为可持续燃料生产提供新途径。 引言 甲烷(CH 4 )是天然气 ...
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