氢氧化过氧化氢的光催化制备新方法。通过Mannich反应合成苯并恶嗪并经聚合、球磨制得微米级催化剂Micro-PBZ,在可见光下O2饱和水溶液中实现86.39 μmol·h?1的高产率,11次循环稳定性良好。DFT计算表明其共轭结构、 tertiary胺基团及π-π堆积促进电荷分离和O2活化,抗 ...
The Nature Index 2025 Research Leaders — previously known as Annual Tables — reveal the leading institutions and countries/territories in the natural and health sciences, according to their output in ...
The Nature Index 2025 Research Leaders — previously known as Annual Tables — reveal the leading institutions and countries/territories in the natural and health sciences, according to their output in ...
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Normal aerobic metabolism (via processes such as photosynthetic and respiratory electron transport chains) in plants yields varied reactive oxygen species (ROS) such as singlet oxygen (1O2), ...
自1818年首次发现过氧化氢(H2O2)以来,它因其高活性氧含量、广泛的pH适应性和无毒副产物(仅为水和氧气)而备受世人瞩目,被视为最有价值的化学品之一,因此广泛应用于如漂白、消毒、污染物降解及化学有机合成等多个工业领域。然而,H2O2的大规模工业 ...
环氧丙烷(PO)是生产聚氨酯、聚酯、丙二醇等工业化学品的重要中间体。目前,生产PO的主要方法是氯醇法和共氧化法,这两种方法的加工过程都很复杂,而且容易产生多种有害副产品。以钛硅分子筛(TS-1)为催化剂,H2O2为氧化剂,甲醇(CH3OH)为溶剂的H2O2氧化生产PO ...
Introduction: Reactive oxygen species (ROS)-mediated therapies have typically been considered as noninvasive tumor treatments owing to their high selectivity and efficiency. However, the harsh tumor ...
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